Journal
SCIENCE CHINA-CHEMISTRY
Volume 62, Issue 3, Pages 331-335Publisher
SCIENCE PRESS
DOI: 10.1007/s11426-018-9387-7
Keywords
silver cluster; photoluminescence switch; structure transformation; acetonitrile response
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Funding
- National Natural Science Foundation of China [21671175]
- Program for Science & Technology Innovation Talents in Universities of Henan Province [164100510005]
- Program for Innovative Research Team (in Science and Technology) in Universities of Henan Province [19IRTSTHN022]
- Zhengzhou University
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A new 1D silver cluster-assembled complex Ag(10)bpy-CH3CN exhibiting intense photoluminescence was reported. Upon the loss of coordinated acetonitrile, Ag(10)bpy-CH3CN form Ag(10)bpy with Ag10S6 cores slightly distorted, being accompanied with photoluminescence quenching. Inverse process can be realized by treating Ag(10)bpy with acetonitrile and shows a selectively erasable photoluminescent switch.
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