Journal
SCIENCE
Volume 362, Issue 6412, Pages 311-314Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/science.aap7883
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Funding
- Japan Society for the Promotion of Science (JSPS) under the Global COE Program
- University of Tokyo
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan
- Japan Science Technology Agency (JST)
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The development of highly reactive and stereoselective catalytic systems is required not only to improve existing synthetic methods but also to invent distinct chemical reactions. Herein, a homogenized combination of nickel-based Lewis acid-surfactant-combined catalysts and single-walled carbon nanotubes is shown to exhibit substantial activity in water. In addition to the enhanced reactivity, stereoselective performance and long-term stability were demonstrated in asymmetric conjugate addition reactions of aldoximes to furnish chiral nitrones in high yields with excellent selectivities. The practical and straightforward application of the designed catalysts in water provides an expedient, environmentally benign, and highly efficient pathway to access optically active compounds.
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