4.3 Article Proceedings Paper

Direct esterification of phosphinic and phosphonic acids enhanced by ionic liquid additives

Journal

PURE AND APPLIED CHEMISTRY
Volume 91, Issue 1, Pages 59-65

Publisher

WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2018-1008

Keywords

esterification; ICPC-22; ionic liquid; microwave irradiation; phosphinic derivatives; phosphonic derivatives

Funding

  1. National Research Development and Innovation Fund [K119202]

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The beneficial combination of microwave (MW) and ionic liquid (IL) additives was exploited in the direct esterification of a series of acyclic phosphinic and phosphonic acids giving rise to phenyl-H-phosphinates/methyl-phenylphosphinates/diphenylphosphinates and phenylphosphonic mono- and diesters, respectively. The latter is the first example for the direct esterification of a phosphonic acid.

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