Journal
PURE AND APPLIED CHEMISTRY
Volume 91, Issue 3, Pages 389-396Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2018-0913
Keywords
benzyne; biomass; Diels-Alder cycloaddition; 5-(hydroxymethyl)furan-2-carboxylic acid; monomers; POC-17; value added products
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Funding
- National Science Foundation [IIA-1355466]
- ND-EPSCoR
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A series of renewable novel bicyclic AB type polyester precursors have been prepared in good overall yield from lignocellulosic biomass. These advancements take full advantage of the differing oxidation states of functional groups in 5-(hydroxymethyl) furfural by chemoselective preparation of furanic hydroxy esters and applying benzyne-Diels-Alder cycloaddition/aromatization strategies.
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