4.6 Article

Green synthesis of metal oxide nanoparticles and their catalytic activity for the reduction of aldehydes

Journal

PROCESS BIOCHEMISTRY
Volume 77, Issue -, Pages 48-56

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.procbio.2018.12.001

Keywords

Cocos nucifera; Metal oxide nanoparticles; Reduction; Aldehyde; Nanocatalysis

Funding

  1. DST-SERB, India [ECR/2016/001523]

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In the present work, a green synthesis of Metal Oxide nanoparticles was demonstrated using the freshly prepared aqueous extract of the immature fruit of Cocos nucifera and the MO nanoparticles were characterized by the analytical techniques such as UV vis, FT-IR, XRD, SEM, TEM and EDAX. Characterization techniques confirmed that the biomolecules involved in the formation of nanoparticles and also they stabilized the nanoparticles. The synthesized MO nanoparticles were used as catalysts for the reduction of aromatic aldehydes. The reduction was done at mild reaction conditions using ammonium formate as a green hydrogen donor and the corresponding alcohols were obtained in 2-24 h with excellent yields. The reduction reaction was optimized using various solvents, loading of catalyst and at different temperatures.

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