Journal
POLYMERS FOR ADVANCED TECHNOLOGIES
Volume 30, Issue 3, Pages 608-619Publisher
WILEY
DOI: 10.1002/pat.4497
Keywords
compatibilization; morphology; SEBS; thermoplastic elastomers; TPU
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Thermoplastic elastomers (TPEs) based on new generation ultrahigh molecular weight styrene-ethylene-butylene-styrene (SEBS) and thermoplastic polyurethane (TPU) are developed and characterized especially for automotive applications. Influence of maleic anhydride grafted styrene-ethylene-butylene-styrene (SEBS-g-MA) and maleic anhydride grafted ethylene propylene rubber (EPM-g-MA) as compatibilizers has been explored and compared on the blends of SEBS/TPU (60:40). The amount of compatibilizers was varied from 0 to 10 phr. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) studies revealed the dramatic changes from a nonuniform to finer and uniform dispersed phase morphology. This was reflected in various mechanical properties. SEBS-g-MA modified blends showed higher tensile strength. EPM-g-MA modified blends also displayed considerable improvement. Elongation at break (EB) was doubled for the entire compatibilized blends. Fourier-transform infrared spectrometry (FTIR) confirmed the chemical changes in the blends brought about by the interactions between blend components and compatibilizers. Both SEBS-g-MA and EPM-g-MA had more or less similar effects in dynamic mechanical properties of the blends. Additionally, melt rheological studies have also been pursued through a rubber process analyzer (RPA) to get a better insight.
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