Journal
POLYMER
Volume 158, Issue -, Pages 120-129Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2018.10.059
Keywords
Polyurethane; Diselenide; Graphene oxide; Photo-thermal; Shape memory; Self-healing
Categories
Funding
- National Natural Science Foundation of China [21474065]
- Sichuan Province Science and Technology Support Project [2017GZ0422]
- Fundamental Research Funds for the Central Universities [2012017yjsy179]
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In this work, polyurethane/functionalized graphene oxide composites containing diselenide bonds were fabricated by covalently incorporating functionalized graphene oxide (FGO) into hydroxyl-terminated polyurethane prepolymers via in-situ polymerization. It was found that the isocyanate terminated molecules were covalently attached onto the graphene oxide surface, and the FGO could act as a multifunctional reinforcer in mechanical and photo-thermal properties of polyurethane composites. Significant enhancements of mechanical, thermal transport, and crystallization performances of composites were observed with the incorporation of 2 wt% of FGO. Due to the photo-thermal and crystallization-induced effects of FGO as well as the exchangeable characteristic of diselenide bonds, the PID-FGO2 composite exhibited both shape memory and repeatable self-healing functions upon exposure to near infrared (NIR) irradiation. In particular, the introduction of diselenide bonds could greatly improve the healing efficiency from similar to 45% to similar to 90%, and the healing efficiencies were maintained above 75% even after five healing cycles. Such favorable healing is acquired by the photo-thermal response, shape memory effect, and diselenide exchange reaction simultaneously, and the shape memory effect is of great importance for assisting the healing process. We expect that this work could provide a viable avenue for multi functional composite materials.
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