4.5 Article

Covalent immobilization of Co complex on the surface of SBA-15: Green, novel and efficient catalyst for the oxidation of sulfides and synthesis of polyhydroquinoline derivatives in green condition

Journal

POLYHEDRON
Volume 158, Issue -, Pages 25-35

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2018.10.054

Keywords

SBA-15; Cobalt; Heterogeneous catalyst; Sulfoxide; Polyhydroquinoline

Funding

  1. University of Kurdistan
  2. University of Ilam

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In this work, a green and novel catalyst was prepared through immobilization of cobalt complex on the surface of mesostructured SBA-15 and characterized by TGA, SEM, FT-IR, EDX, ICP, BET and X-ray mapping analytical methods. This mesostructural material was used as an efficient and green interphase catalyst for the oxidation reactions and synthesis of polyhydroquinoline derivatives. All reactions were performed in short times and good yields. Moreover, the prepared catalyst could be used up to six runs without significant degradation in its catalytic activity or cobalt leaching. (C) 2018 Elsevier Ltd. All rights reserved.

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