Journal
POLIMEROS-CIENCIA E TECNOLOGIA
Volume 28, Issue 5, Pages 381-388Publisher
ASSOC BRASIL POLIMEROS
DOI: 10.1590/0104-1428.04917
Keywords
plasticization poly(lactic acid); oligoesters; trimethylene sebacate; cast films
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Funding
- Conselho Nacional de Pesquisa Cientifica e Tecnologica - CNPq [310917/2014-0]
- FAPERJ [E-26/201.304/2014]
- CAPES
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The biodegradable aliphatic oligoester oligo(trimethylene separate) (OTS) was synthesized by polycondensation and used to plasticize poly(lactic acid) (PLA). Casting films of PLA and PLA/OTS with concentrations of 1, 5 and 10 wt.% were prepared, and these films were characterized by thermal analyses, crystallinity, theology and mechanical tests. DSC revealed the decrease in the T-g of PLA films with addition of the oligomer and a partial immiscibility. Addition of OTS to PLA slightly decrease the thermal stability as well as increase the degree of crystallinity of these films. Dynamic-mechanical analyses of casting films showed that the PLA/OTS system presented lower storage modulus than PLA and mechanical test revealed an increased in the elongation at break for PLA films containing the oligoester. The results make possible to conclude that the oligomer synthesized from bio-based monomers acts as a plasticizer of PLA increasing the PLA ductility.
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