Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 194, Issue 3, Pages 210-214Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2018.1539489
Keywords
Supported phosphine oxide; hexafluoroisopropanol; Beckmann rearrangement; ketoximes
Categories
Funding
- Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology [BM2012110]
- Advanced Catalysis and Green Manufacturing Collaborative Innovation Center of Changzhou University
- China Postdoctoral Science Foundation [2018M632289]
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A polystyrene-supported phosphine oxide-catalysed Beckmann rearrangement of ketoximes in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) has been developed. Good substrate compatibility, mild reaction conditions, good yields as well as the reusability of the catalyst/solvent made this procedure more environmentally benign.
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