Journal
ORGANOMETALLICS
Volume 37, Issue 21, Pages 3654-3658Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00621
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Funding
- NSERC of Canada
- Canadian Foundation for Innovation
- Canada Research Chair
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We demonstrate that tris(pentafluorophenyOborane, B (C6F5)(3), is shown to be an effective catalyst for the hydroarylation of olefins to yield substituted phenols. This system features fast reaction times, mild conditions, and good yields for a select scope of olefinic substrates and various phenols, resulting in C-C bond formation. Experimental data support two possible mechanisms, where the Lewis acid can activate either the olefin or the phenol as the first step in the catalytic mechanism.
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