Journal
ORGANOMETALLICS
Volume 37, Issue 21, Pages 3687-3697Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00394
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Funding
- National Science Foundation [CHE1213774, ACI-1053575]
- National Institute of Health [GM076125]
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The investigation of the stereoelectronic influence of N-aryl substituted NHC ligands on Ni(0) is reported. The structural analysis of a family of [(NHC)Ni(styrene)(2)] complexes are correlated to known literature parameters (TEP and %V-Bur). The analysis involved NMR spectroscopic techniques and X-ray crystallography analysis of the isolated [(NHC)Ni(styrene)(2)] complexes. The synthesis and characterization of this user-friendly and easy accessible Ni(0) precatalysts can be realized in a two-step synthesis starting from deprotonation of the imidazolium salt followed by direct coordination onto nickel in the presence of excess styrene.
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