Journal
ORGANOMETALLICS
Volume 37, Issue 21, Pages 3644-3648Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00573
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Funding
- National Science Foundation [CHE-1464661]
- University of Pennsylvania
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Upon exposure of [(BPI)M(CH3)] (M = Pd, Pt, BPI = 1,3-bis(2-pyridylimino)isoindole) complexes to O-2, direct insertion was observed to generate the O-2 insertion products (BPI)M(OOCH3). Kinetic and mechanistic analyses of the O-2 insertion reaction support a radical chain substitution mechanism. Reproducible kinetics were observed in the presence of a radical initiator. The release of methanol was subsequently observed from the M-OOCH3 products.
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