Journal
ORGANOMETALLICS
Volume 38, Issue 2, Pages 210-212Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.8b00798
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Funding
- Development of Innovative Catalytic Processes for Organosilicon Functional Materials project from the New Energy and Industrial Technology Development Organization (NEDO)
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The catalytic reduction of alkoxysilanes with the borane HBpin (pin = pinacolato) was achieved using a metallocene-type yttrium complex as a catalyst precursor. Mechanistic study supported the pivotal role of the rigid metallocene structure of the catalyst, which bears two bulky eta(5)-C5Me4SiMe3 ligands, in suppressing the coordination of the side product MeOBpin that is generated during the reaction.
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