Journal
ORGANIC LETTERS
Volume 20, Issue 20, Pages 6601-6605Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02972
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Funding
- JSPS KAKENHI [JP16H04109, JP18H04254, JP18H04409, JP18K14212]
- Toyota Physical and Chemical Research Institute
- Asahi Glass Foundation
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As a new transformation of organosulfur compounds, intramolecular desulfitative coupling of diaryl sulfones to the corresponding biaryls has been developed with the aid of nickel-NHC catalysts. This catalytic elimination of SO2 was also applicable to alkenyl aryl sulfone to furnish the corresponding alkenyl arene.
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