Journal
ORGANIC LETTERS
Volume 20, Issue 23, Pages 7740-7743Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03549
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- CSIR, New Delhi [02(0307)/17/EMR-II]
- CSIR-New Delhi (CSIR-SRF)
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A metal-free visible-light-promoted oxidative coupling between thiols and arylhydrazines has been developed to afford diaryl sulfides using a catalytic amount of rose bengal as photocatalyst under aerobic conditions. A library of unsymmetrical diaryl sulfides with broad functionalities was synthesized in good yields at room temperature. The present methodology is also applicable to benzo[d]thiazole-2-thiols, benzo[d]oxazole-2-thiol, 1H-benzo[d]imidazole-2-thiols, and 1H-imidazole-2-thiol.
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