Journal
ORGANIC LETTERS
Volume 20, Issue 23, Pages 7712-7716Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03446
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Funding
- National Research Foundation (NRF) of the Korea-Basic Science Research Program [2017R1D1A1B03029926]
- Dongguk University Research Fund
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A scalable and operationally simple method is described that allows for the chemoselective deoxygenation of a wide range of N-heterocyclic N-oxides (a total of 36 examples). This visible-light-induced protocol features the use of only commercially available reagents, room-temperature conditions, and unprecedented chemoselective removal of the oxygen atom in a quinoline N-oxide in the presence of a pyridine N-oxide in the same molecule through the judicious selection of a photocatalyst.
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