Journal
ORGANIC LETTERS
Volume 21, Issue 2, Pages 567-570Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03922
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Funding
- National Institutes of Health NIGMS [GM124004]
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A complementary process to the Pauson-Khand annulation is described that is well suited to forging densely substituted/oxygenated cyclopentenone products (including fully substituted variants). The reaction is thought to proceed through a sequence of metallacycle-mediated bond-forming events that engages an internal alkyne and a beta-keto ester in an annulation process that forges two C-C bonds. A variant of this annulation process has also been established that delivers deoxygenated cyclopentenones that lack the allylic tertiary alcohol.
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