Journal
ORGANIC LETTERS
Volume 21, Issue 2, Pages 535-539Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03847
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Funding
- National Natural Science Foundation of China [21672199, 21790333, 21702197]
- CAS Interdisciplinary Innovation Team
- Anhui provincial Natural Science Foundation [1708085MB28]
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A highly chemo- and regioselective 1,4-aminomethylamination of simple enynes with aminals to allenic 1,5-diamines by taking advantage of C-N bond activation has been reported. The reaction proceeds under mild reaction conditions and can be performed under lower catalyst loading (0.1 mol %) with high efficiency and broad substrate scope.
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