Journal
ORGANIC LETTERS
Volume 21, Issue 2, Pages 469-472Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03710
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Funding
- National Natural Science Foundation of China
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A visible-light-induced radical cascade cyclization of 2-isocyanoaryl thioethers for the synthesis of 2-CF2/CF3-containing benzothiazoles has been developed. Sodium sulfite can participate in the photocatalytic cycle as a reductant that efficiently transforms Ir4+ into Ir3+ to promote the fluoroalkylation under mild reaction conditions.
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