Journal
ORGANIC LETTERS
Volume 21, Issue 1, Pages 223-227Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03668
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- SERB, New Delhi
- IRCC, IIT Bombay
- IIT Bombay
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A single alkynyl vinylogous carbonate was elaborated to tetrasubstituted furan or dihydrofuran via a cascade inter-intramolecular radical reaction by changing the radical being added. The strategy could be used in the synthesis of polycyclic heterocycles as well as bis-furan exhibiting atropisomerism. Installation of a new furan motif on the existing one was feasible by iteration. Stannyl dihydrofuran derivative was used in Stille coupling, whereas intramolecular Friedel-Crafts acylation on the furan gave furanonaphthol.
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