Journal
ORGANIC LETTERS
Volume 21, Issue 1, Pages 330-334Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03934
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Funding
- NSFC [21672184, 21861042]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13095]
- Program for Innovative Research Team (in Science and Technology) in University of Yunnan Province, Yunling Scholar of Yunnan Province, Yunnan Province Government [2018FY001(016)]
- National Postdoctoral Program for Innovative Talents [BX201600129]
- China Postdoctoral Science Foundation [2016M602726]
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The first highly stereoselective intermolecular catalytic asymmetric dearomatization (CADA) of alpha-naphthols through C-C formation and the first asymmetric allylic dearomatization of naphthols by chiral organocatalysis have been achieved. These new and complete atom-economic reactions provide enantioriched alpha- and beta-naphthalenones bearing an all-carbon quaternary center.
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