Journal
ORGANIC LETTERS
Volume 21, Issue 3, Pages 745-748Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b03980
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Funding
- National Natural Science Foundation of China [21602158]
- Zhejiang Provincial Natural Science Foundation [LY19B020011]
- State Key Laboratory of Structural Chemistry [20170037]
- Opening Project of Zhejiang Provincial Top Key Discipline of Pharmaceutical Sciences [201723]
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The first example of copper-catalyzed four-component coupling reaction of aryl iodides, Se powder, secondary amines, and maleimides is developed. This reaction provides an efficient and concise route to access amino-arylselenated maleimides via double C-Se bonds and C-N bond formation. The appealing features of this transformation are the use of Se powder as a selenating reagent, a green catalytic system, a wide range of substrate scope, and late-stage selenation of bioactive compounds.
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