4.8 Article

Multiphase Media Antiadhesive Coatings: Hierarchical Self-Assembled Porous Materials Generated Using Breath Figure Patterns

Journal

ACS NANO
Volume 10, Issue 12, Pages 11087-11095

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsnano.6b05961

Keywords

antiadhesion; multiple media; breath figure; porous structure; hierarchical self-assembly

Funding

  1. National Research Fund for Fundamental Key Projects [2014CB931802, 2013CB834705]
  2. National Natural Science Foundation of China [51541301, 51673010]
  3. Fundamental Research Funds for the Central Universities [YWF-16-BJ-Y-72]

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The cleaning of interface pollutants typically consumes a large amount of energy. Therefore, the development of multiphase media antiadhesive materials is urgently required to meet the demand of energy savings and environmental protection. In this study, the antiadhesive properties toward several liquid droplets and bubbles in multiple media are demonstrated on a porous Fe2O3 coating, which is prepared via a facile spin coating-assisted breath figure approach and a phase separation strategy. The prominent antiadhesive characteristic of these porous surfaces lies in their high-surface-energy hierarchical micro/nanoscale structure, which easily entraps one medium (oil or water) in the pore and repels other unmixable liquids and air bubbles. In addition, we successfully demonstrate an antifouling application of the coating, which shows excellent antiadhesive and super-antiwetting characteristics under multiple liquids. Our work extends relevant antiadhesion research from a single medium to multiple media and promises to broaden the applications of antiadhesive materials in sophisticated activities liquid environments, such as marine antifouling or pipeline transportation. performed under complicated

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