Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 41, Pages 27868-27876Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b10700
Keywords
nanofoaming; nickel nanowire; supercapacitor; volumetric capacity; energy storage
Funding
- National Key Research and Development Program of China [2016YFC0102700]
- National Natural Science Foundation of China [61671299, 81670958]
- Shanghai Science and Technology Grant [16JC1402000]
- Program of Shanghai Academic/Technology Research Leader [15XD1525200]
- Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning
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Three-dimensional free-standing film electrodes have aroused great interest for energy storage devices. However, small volumetric capacity and low operating voltage limit their practical application for large energy storage applications. Herein, a facile and novel nanofoaming process was demonstrated to boost the volumetric electrochemical capacitance of the devices via activation of Ni nanowires to form ultrathin nanosheets and porous nanostructures. The as-designed free-standing Ni@Ni(OH)(2) film electrodes display a significantly enhanced volumetric capacity (462 C/cm(3) at 0.5 A/cm(3)) and excellent cycle stability. Moreover, the as developed hybrid supercapacitor employed Ni@Ni(OH)(2) film as positive electrode and graphene-carbon nanotube film as negative electrode exhibits a high volumetric capacitance of 95 F/cm(3) (at 0.25 A/cm(3)) and excellent cycle performance (only 14% capacitance reduction for 4500 cycles). Furthermore, the volumetric energy density can reach 33.9 mWh/cm(3), which is much higher than that of most thin fihn lithium batteries (1-10 mWh/cm(3)). This work gives an insight for designing high-volume three-dimensional electrodes and paves a new way to construct binder-free film electrode for high-performance hybrid supercapacitor applications.
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