Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 11, Pages 7370-7380Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b00264
Keywords
Fe3O4/C; nanoring; hydrothermal method; magnetic property; microwave absorption
Funding
- National Natural Science Foundation of China [51102215]
- Public Utility Items of Zhejiang Province [2015C31022]
- Natural Science Foundation of Zhejiang Province [LY14B010001]
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Using elliptical iron glycolate nanosheets as precursors, elliptical Fe3O4/C core-shell nanorings (NRs) [25 +/- 10 nm in wall thickness, 150 +/- 40 nm in length, and 1.6 +/- 0.3 in long/short axis ratio] are synthesized via a one-pot hydrothermal route. The surface-poly(vinylpyrrolidone) (PVP)-protected-glucose reduction/carbonization/Ostwald ripening mechanism is responsible for Fe3O4/C NR formation. Increasing the glucose/precursor molar ratio can enhance carbon contents, causing a linear decrease in saturation magnetization (M-s) and coercivity (H-c). The Fe3O4/C NRs reveal enhanced low frequency microwave absorption because of improvements to their permittivity and impedance matching. A maximum R-L value of -55.68 dB at 3.44 GHz is achieved by Fe3O4/C NRs with 11.95 wt % C content at a volume fraction of 17 vol %. Reflection loss (R-L) values (<=-20 dB) are observed at 2.11-10.99 and 16.5-17.26 GHz. Our research provides insights into the microwave absorption mechanism of elliptical Fe3O4/C core shell NRs. Findings indicate that ring-like and core shell nanostructures are promising structures for devising new and effective microwave absorbers.
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