4.8 Article

A Flexible and Thin Graphene/Silver Nanowires/Polymer Hybrid Transparent Electrode for Optoelectronic Devices

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 45, Pages 31212-31221

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b09056

Keywords

flexible transparent electrode; metal nanowires; graphene; sandwich; up-to-bottom

Funding

  1. Basic Research Program of China [2013CB328705]
  2. National Natural Science Foundation of China [11574248, 61275034]
  3. Ph.D. Programs Foundation of Ministry of Education of China [20130201110065]
  4. International Cooperation by Shaanxi [2015KW-008]
  5. China Postdoctoral Science Foundation [2016M590947]
  6. Fundamental Research Funds for the Central Universities [xjj2016031]

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A typical thin and fully flexible hybrid electrode was developed by integrating the encapsulation of silver nanowires (AgNWs) network between a monolayer graphene and polymer film as a sandwich structure. Compared with the reported flexible electrodes based on PET or PEN substrate, this unique electrode exhibits the superior optoelectronic characteristics (sheet resistance of 8.06 Omega/square at 88.3% light transmittance). Meanwhile, the specific up-to-bottom fabrication process could achieve the superflat surface (RMS = 2.58 nm), superthin thickness (similar to 8 mu m thickness), high mechanical robustness, and lightweight. In addition, the strong corrosion resistance and stability for the hybrid electrode were proved. With these advantages, we employ this electrode to fabricate the simple flexible organic light-emitting device (OLED) and perovskite solar cell device (PSC), which exhibit the considerable performance (best PCE of OLED = 2.11 cd/A(2); best PCE of PSC = 10.419%). All the characteristics of the unique hybrid electrode demonstrate its potential as a high-performance transparent electrode candidate for flexible optoelectronics.

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