4.8 Article

Electroless Nickel Deposition: An Alternative for Graphene Contacting

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 45, Pages 31359-31367

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b08290

Keywords

contacting graphene; electroless nickel; contact resistance; transmission line method; interface characterization

Funding

  1. EPRSC [EP/I015930/1]
  2. Leverhulme Trust [VPI-2013-003]
  3. British Council [UKIERI-TRP-2012/13-0010]
  4. EPSRC [EP/I015930/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/I015930/1] Funding Source: researchfish

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We report the first investigation into the potential of electroless nickel deposition to form ohmic contacts on single layer graphene. To minimize the contact resistance on graphene, a statistical model was used to improve metal purity, surface roughness, and coverage of the deposited film by controlling the nickel bath parameters (pH and temperature). The metalized graphene layers were patterned using photolithography and contacts deposited at temperatures as low as 60 degrees C. The contact resistance was 215 +/- 23 Omega over a contact area of 200 mu m X 200 mu m, which improved upon rapid annealing to 107 +/- 9 Omega. This method shows promise toward low-cost and large-scale graphene integration into functional devices such as flexible sensors and printed electronics.

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