Journal
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 39, Issue 4, Pages 1186-1192Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2018.12.049
Keywords
Ceramics; Oxides; Hot-pressing; Texture; Electrical properties
Categories
Funding
- Spanish MINECO-FEDER [MAT2017-82183-C3-1-R]
- Gobierno de Aragon-FEDER [T54-17R]
- i3N [UID/CTM/50025/2013]
- CICECO-Aveiro Institute of Materials [UID/CTM/50011/2013]
- COMPETE 2020 Program [POCI-01-0145-FEDER-031875]
- COMPETE 2020 Program
- FEDER, POCI in its FEDER/FNR component, under the PT2020 Partnership Agreement
- FCT (Portugal) [SFRH/BPD/111460/2015, IF/00302/2012]
- FCT grant [SFRH/BPD/124238/2016]
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This work explores the possibilities for a further enhancement of the thermoelectric properties of Ca3Co4O9 by Sr-doping combined with hot-pressing. Modified hot-pressing process resulted in highly-textured and dense ceramics. Sr-doping significantly improves electrical properties, resulting in extremely large power factor (1.2 mW/K-2 m at 800 degrees C) due to simultaneous electrical resistivity decrease and Seebeck coefficient increase. The main effect on cumulative electrical performance is provided by the Seebeck coefficient, reaching 270 mu V/K at 800 degrees C. XPS revealed relatively high average cobalt oxidation state at room temperature (+ 3.3), compared to materials produced by conventional sintering. The results of combined XPS and Auger electron spectroscopy emphasize the importance of high densification in Ca3Co4O9-based ceramics for preventing phase decomposition and interaction with CO2 and moisture. Still, despite the exceptional electrical performance, the calculated figure-of-merit (estimated as 0.29 at 800 degrees C) is around the best reported in the literature due to a high thermal conductivity (4.4 W/K m at room temperature).
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