Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 30, Pages 19680-19690Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b04746
Keywords
Frank van der Merwe layer-by-layer growth; 3D growth; Pt nanoparticles; nanoparticle mono ayers; AOT reverse micelles; nonpolar suspensions; nanoparticle charging; electrophoretic deposition
Funding
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1361068] Funding Source: National Science Foundation
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We report on the formation of Pt nanoparticle monolayers by electrophoretic deposition from nonpolar solvents. First, the growth kinetics of Pt nanoparticles prepared by the reverse micelle technique are described in detail. Second, a model of nanoparticle charging in nonpolar media is discussed and methods to control the nanoparticle charging are proposed. Finally, essential parameters of the electrophoretic deposition process to control the deposition of nanoparticle monolayers are discussed and mechanisms of their formation are analyzed.
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