Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 141, Issue 7, Pages 2800-2813Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b11790
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Funding
- U.S. National Science Foundation [CHE-1265964, CHE-1661612]
- U.S. National Institute of General Medical Sciences [R01GM098601]
- NIH
- NSERC [NIH F32GM125149, NSERC PDF-502407]
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Radical fragment coupling reactions that unite intricate subunits have become an important class of transformations within the arena of complex molecule synthesis. This Perspective highlights some of the early contributions in this area, as well as more modern applications of radical fragment couplings in the preparation of natural products. Additionally, emphasis is placed on contemporary advances that allow for radical generation under mild conditions as a driving force for the implementation of radical fragment couplings in total synthesis.
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