4.8 Article

Equipment-Free Deposition of Graphene-Based Molybdenum Oxide Nanohybrid Langmuir-Blodgett Films for Flexible Electrochromic Panel Application

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 33, Pages 21539-21544

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b04985

Keywords

electrochromic materials; electrodes; hybrid materials; molybdenum; Langmuir-Blodgett

Funding

  1. Center for Bio-Inspired Solar Fuel Production, an Energy Frontier Research Center - US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001016]
  2. Department of Defense through the Army Research Office (ARO) [W911NF-12-1-0420]

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The potential electrochromic application of graphene-based nanohybrids is hampered by the challenges in interfacing the electrochromic nanoparticles with graphene at atomic scale and in fabricating their thin film on the substrate through a scalable method. In an effort to overcome these challenges, we demonstrate a highly dispersible graphene-based molybdenum oxide nanohybrid (mRGO-MoO3-x) for flexible electrochromic application. With only a squeeze pipet, mRGO-MoO3-x could be deposited with a high coverage on various substrates through a scalable equipment-free LangmuirBlodgett film deposition method. By taking advantage of high transmittance benefited from its remarkable thinness, the mRGO-MoO3-x Langmuir-Blodgett film shows a superior reversible electrochromic property with high coloration efficiency on both hard and flexible substrates.

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