Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 49, Pages 16899-16903Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b09933
Keywords
-
Categories
Funding
- Japan Society for the Promotion of Science [16H04125, 15H05480, 17K19185]
- JST ACT-C, Japan [JPMJCR12YH]
- [17H06444]
- [17H05391]
- Grants-in-Aid for Scientific Research [16H04125, 17K19185, 15H05480] Funding Source: KAKEN
Ask authors/readers for more resources
Visible-light-driven catalytic reduction of CO2 is at the heart of artificial photosynthesis. Here, we demonstrate the first example of a Ru complex that can function both as a photosensitizer and catalyst for CO2 reduction. The catalyst exhibited excellent activity for CO evolution with a high turnover number (TON, 353 for 24 h), reaction rate (TOF, 14.7 h(-1)), and product selectivity (97%) under visible-light irradiation. We also succeeded in selective product formation (CO or HCOOH) by changing the basicity of the reaction media. This finding will open new avenues for visible-light-driven photoredox catalysis using Ru-based function-integrated photocatalysts.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available