Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 45, Pages 15194-15199Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b10298
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Funding
- State Key Laboratory of Elemento-organic Chemistry
- National Key Research and Development Program of China [2016YFA0602900]
- NFSC [21522205, 21672110]
- Fundamental Research Funds for the Central Universities
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A catalytic ring-opening reaction of epoxides by nucleophilic trifluoromethoxylation of trifluoromethyl arylsulfonate has been developed based on the use of a cobalt catalyst. This reaction provides an efficient, simple route for directly construction of a wide range of vicinal trifluoromethoxyhydrins under mild conditions. In addition, this method can convert terminal epoxides into target products with good chemo- and regioselectivity.
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