Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 8, Issue 38, Pages 25571-25577Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b02047
Keywords
CuI-RGO composite; nanophosphor; cathodoluminescence; field-emission display; density functional theory
Funding
- Council of Scientific and Industrial Research (CSIR), the Government of India
- West Bengal State Govt.
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Field-emission displays (FEDs) constitute one of the major foci of the cutting edge materials research because of the increasingly escalating demand for high-resolution display panels. However, poor efficiencies of the concurrent low voltage cathodoluminescence (CL) phosphors have created a serious bottleneck in the commercialization of such devices. Herein we report a novel cuI-RGO composite nanophosphor that exhibits-bright red :emission under low voltage electron beam excitation. Quantitative assessment of CL-spectra reveals that cuI-RGO nanocoMposite phosphor leads to,the 4-fold enhancement in the CL intensity as compared to the pristine atI counterpart. Addition of RGO in the-Cul matrix facilitates efficient triggering of luminescence centers thatare.activated by local-electric.field enhancement at the CuI-RGO contact points. In addition, conducting RGO also reduces-the negative loading problem on the surfaCe of the nanophosphor composite. The concept presented here op-ens up a novel generic route for enhancing CL intensity of the existing (nano)phosphors as well as 'validates the bright prospects of the CuI,RGO composite nanophosphor in this rapidly growing field.
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