4.6 Article

Fabrication of h-BN@PbWO4 with a facile sol-gel method towards enhanced photocatalytic and radiation shielding properties

Journal

JOURNAL OF SOLID STATE CHEMISTRY
Volume 269, Issue -, Pages 594-599

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2018.10.043

Keywords

Core-shell structure; Photocatalytic activity; Radiation shielding

Funding

  1. National Natural Science Foundation of China [11747042]
  2. Science and Technology Development Foundation of China Academy of Engineering Physics [xk201701]
  3. Open Fund of State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials [15zxfk06, 16kffk01, 17kffk07]

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Designing versatile materials for radiation protection is of great significance to the rapid development of nuclear technology. Here, BN@PbWO4 core-shell particles are successfully prepared via a facile sol-gel method. The structure and morphology of products are determined by XRD, SEM, TEM and FTIR techniques. Compared with PbWO4 and h-BN, BN@PbWO4 exhibits much more excellent photocatalytic ability to degrade the organic dye Rhodamine B (RhB). Furthermore, it also has a good ability to jointly shield neutron and gamma radiations, especially better gamma radiation shielding in comparison with PbWO4. This work provides an integrated solution with the material that could deal with organic wastes and shield complex radiations in nuclear industry.

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