Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 57, Issue 1, Pages 7-12Publisher
WILEY
DOI: 10.1002/pola.29266
Keywords
dynamic covalent polymerization; inverse vulcanization; nucleophilic activation; organocatalysis; sulfur
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Funding
- NSF [DMR-1607971, CHE-1305773]
- NRF for the National Creative Research Initiative Center for Intelligent Hybrids [2010-0018290]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1305773] Funding Source: National Science Foundation
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The accelerator effect of amine activators N-methylimidazole and 4-vinylaniline (4-VA) on inverse vulcanization and dynamic covalent polymerization (DCP) has been investigated. The sulfur polymer with self-activation comonomer 4-VA could also be used for low temperature DCP to incorporate some volatile monomers. Those approaches provide a new synthetic and rate accelerated processes to activate S-8 for copolymerization processes with functional comonomers at lower temperatures and under a broader range of reaction conditions.
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