4.6 Review

Nonequilibrium electron and phonon dynamics in advanced concept solar cells

Journal

JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 52, Issue 9, Pages -

Publisher

IOP Publishing Ltd
DOI: 10.1088/1361-6463/aaf750

Keywords

photovoltaics; noequilibrium dynamics; hot carriers; Monte Carlo simulation; multiexciton generation; semiconductor devices; nanowires

Funding

  1. Engineering Research Center Program of the National Science Foundation
  2. Office of Energy Efficiency and Renewable Energy of the Department of Energy under NSF [EEC-1041895]
  3. Institute for Advanced Science (IAS) at the Technical University of Munich
  4. German Research Foundation (DFG) within the Heisenberg program [JI 115/4-2]

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The realization of advanced concept solar cells that circumvent assumptions inherent in the Shockley-Queisser limit depends strongly on a competition between carrier energy relaxation processes to the lattice and high energy processes that do useful work. Here we review the role of ultrafast carrier dynamics in the performance of such advanced concept devices, experimental results to date, and then present theoretical studies of such processes using ensemble Monte Carlo simulation of electrons, holes and phonons, with a particular focus on such processes in multi-quantum well systems, as well as III-V nanowires.

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