Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 123, Issue 5, Pages 3130-3143Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.8b09177
Keywords
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Funding
- CNPq [165106/2014-0]
- Capes [88881.132245/2016-01]
- FAPESP [2015/22711-1]
- Coordenacio de Aperfeicoamento de Pessoal de Nivel Superior Brasil (CAPES) [001]
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Structural stability is a pivotal property required for Nb2O5 to be applied as a solid-acid catalyst in heterogeneous catalytic reactions. When combined with Ni, Nb2O5 produces cheap and active hydrogenation catalysts. Ni-Nb2O5 operates as a bifunctional catalyst and is being widely explored for various catalytic applications without, however, exploring its structural stability and its effects on catalytic activity and durability. Herein we studied two forms of niobia, one with nonuniform morphology and another comprising a nanorod morphology. Various selected Ni loadings were dispersed on the two supports via a deposition-precipitation method. Physical and chemical characterization revealed that morphological control in combination with a highly efficient Ni deposition method is key in producing a structurally stable Ni-Nb2O5 catalyst. High surface area and porosity as exhibited by the Nb2O5 nanorods, in the pseudohexagonal phase, combined with small, well-dispersed Ni particles, provide a structurally stable material up to 500 degrees C, with high acidity (Lewis and Bronsted acid sites). Moreover, the local and long-range order, characterized in situ XANES and XRD), determined the temperature limits for the optimization of metallic Ni particles in relation to the Nb2O5 structure.
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