Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 4, Pages 2243-2251Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02981
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21861019]
- Natural Science Foundation of Jiangxi Province [20161ACB21010]
- Science Fund for Distinguished Young Scholars in Jiangxi Province [20162BCB23023]
Ask authors/readers for more resources
The visible light induced C-H bond thiocyanation on the alpha-site of tertiary enaminones has been realized under metal-free, photocatalytic conditions in the presence of Rose Bengal, which enables the synthesis of thiocyanated alkene derivatives and chromones using NH4SCN as the thiocyano source under an aerobic atmosphere. In addition, employing Ru(bpy)(3)Cl-2 center dot 6H(2)O as the photocatalyst switches the reaction pathway to provide NH2-functionalized thiocyanated enamines via the difunctionalization process consisting of C-H bond thiocyanation and vinyl C-N bond transamination.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available