Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 24, Pages 15524-15532Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02595
Keywords
-
Categories
Funding
- National Science Foundation of China [21772008, 21632002, 21572009, U1606403]
- Guangdong Natural Science Foundation [2016A030306011, 2017TQ04R032]
- Shenzhen Basic Research Program [JCYJ201708180900-44432, JCYJ20160226105337556]
Ask authors/readers for more resources
The formal total synthesis of hybocarpone was achieved in eight steps from commercially available 1,2,4-trimethoxybenzene. Key transformations include a visible-light-promoted benzannulation to construct the key alpha-naphthol intermediate and a modified CAN-mediated dimerization/hydration cascade sequence to generate the vicinal all-carbon quaternary centers in a stereocontrolled manner. The total synthesis of boryquinone was also achieved in seven steps.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available