Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 24, Pages 14978-14986Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02235
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Funding
- National Natural Science Foundation of China [21402070, 21662042]
- Natural Science Foundation of Yunnan Province [2017FA003]
- Analytical & Testing Foundation of Kunming University of Science and Technology [2017T20130137, 2017M20152118097]
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A direct C-sp3-H bond oxidative thioesterification of methyl ketones with aromatic thiols/disulfides promoted by TBAI/K2S2O8 has been developed. The reaction provides successfully a simple and efficient method for the synthesis of functionalized alpha-ketothioesters of aromatic thiols. This practical methodology exhibits readily available starting materials, large-scale applicability, synthetic application, and broad functional group tolerance. A possible mechanism for the transformation is proposed.
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