Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 4, Pages 2061-2071Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b03072
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Funding
- Herman Frasch Foundation for Chemical Research [701-HF12]
- National Science Foundation [CHF-1455163]
- NIGMS Training Grant on Dynamic Aspects of Chemical Biology [T32 GM08545]
- NIH [S10OD016360, S10RR024664]
- NSF [9977422, 0320648]
- NIH Center Grant [P20GM103418]
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A new bench-stable trifluoromethylation reagent, phenyl bromodifluoroacetate, converts readily available alcohols to trifluoromethanes in a Cu-catalyzed deoxytrifluoromethylation reaction. This reaction streamlines access to target biologically active molecules, and should be useful for a variety of medicinal, agricultural, and materials chemists.
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