Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 83, Issue 22, Pages 14210-14217Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02532
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Funding
- National Natural Science Foundation of China [21602105]
- Natural Science Foundation of Jiangsu Province [BK20171460]
- National Key R&D Program of China [2017YFA0204704]
- National Key Basic Research Program of China (973) [2015CB932200]
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Direct and rapid construction of carbazoles has been successfully developed via carbene-catalyzed oxidative formal [4 + 2] annulation of enals with 2-methyl-3-oxoacetate indoles. This metal-free reaction features a broad substrate scope, features good functional-group tolerance, proceeds under mild conditions, and can be easily scaled up.
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