Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 1, Pages 463-471Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02766
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Funding
- National Nature Science Foundation of China [21602169, 21602202]
- China Postdoctoral Science Foundation [2016M592775]
- Xi'an Jiaotong University New Lecturer plan [334100038]
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BF3 center dot OEt2-mediated cross-coupling of (SnMe3)(2) with aryl triazene offers a new strategy for the synthesis of aryl stannane. A variety of synthetically useful aryl trimethylstannanes were produced in moderate to good yields with this metal-free approach. One-pot sequential Stille cross-coupling with different aryl bromides provides a short entry to both symmetrical and unsymmetrical biaryl compounds.
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