Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 1, Pages 401-408Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.8b02334
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Funding
- National Natural Science Foundation [21772046]
- Program of Innovative Research Team of Huaqiao University [Z14 X 0047]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Natural Science Foundation of Fujian Province [2016J01064]
- Huaqiao University
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An expedient strategy for the synthesis of 5-oxazole ketones was developed via homogeneous gold catalysis with 4-MeO-TEMPO as an oxidant. The desired 5-oxazole ketones were achieved in decent yields with an excellent functional group compatibility under mild conditions. The current protocol also represents the first example for merging a gold catalyst and radical chemistry in one-pot synthesis with internal N-propargylamides.
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