Journal
JOURNAL OF MAGNETIC RESONANCE
Volume 298, Issue -, Pages 1-5Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jmr.2018.10.017
Keywords
Overtone NMR; Quadrupolar NMR; Cross-polarisation
Funding
- EPSRC [EP/M023664/1]
- EPSRC
- BBSRC
- University of Warwick through Birmingham Science City Advanced Materials Project 1 - Advantage West Midlands (AWM)
- University of Warwick through Birmingham Science City Advanced Materials Project 2 - Advantage West Midlands (AWM)
- European Regional Development Fund (ERDF)
- EPSRC [EP/P030491/1, EP/K00509X/1, EP/M023664/1] Funding Source: UKRI
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Polarization transfer methods are widely adopted for the purpose of correlating different nuclear species as well as to achieve signal enhancement. Polarization transfer from H-1 to the N-14 overtone transition (Delta m = 2) can be achieved using cross polarization methods under magic-angle spinning conditions, where spin locks of the order of several milliseconds can be obtained on common bio-solids (alpha-glycine and N-acetylvaline). Signal enhancement factors up to 4.4 per scan, can be achieved under favorable conditions, despite MHz-sized quadrupolar interaction. Moreover, we present a detailed theoretical treatment and accurate numerical simulations which are in excellent agreement the unusual experimental matching conditions observed for cross-polarization to N-14 overtone. (C) 2018 Elsevier Inc. All rights reserved.
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