Journal
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
Volume 29, Issue 2, Pages 429-435Publisher
SPRINGER
DOI: 10.1007/s10904-018-1013-6
Keywords
Polymer; Sulphoaluminate cement; Coating; Water absorption; RSM
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Funding
- National Key Research and Development Plan of China [2016YFB0303505]
- National Natural Science Foundation of China, China [51602126, 51672108]
- University of Jinan Postdoctoral Science Foundation [2017M622118, XBH1716]
- State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology) [SYSJJ2018-12]
- 111 Project of International Corporation on Advanced Cement-based Materials [D17001]
- University of Jinan Doctoral Foundation and Scientific Planning Project [XBS1661, XKY1730]
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Polymer-modified cementitious coatings are considered to be one of the most promising waterproofing materials. In this paper, response surface methodology (RSM) is used to optimize composition of silicone modified polyacrylate emulsion (SPA)-sulphoaluminate cement (SAC) composite coating (SSCC) based on improvement of waterproofing property. Being considered as the most important factors, the ratios of SAC to SPA, REP (redispersion emulsion powder) to SPA and SiO2 to SPA are studied. The results show that the quadratic polynomial model fits experiment data fairly well, and R-2 and Adj-R-2 values for water absorption are 0.9852 and 0.9662, respectively. The differences observed from variation of SAC/SPA and REP/SPA are extremely significant. The water absorption of SSCC decreases first and increases afterwards with increasing the ratio of SAC to SPA. And a trend caused by REP/SPA is gradually decreasing. By contrast, the factor of SiO2/SPA is not that significant. The optimal ranges, taken all factors into consideration, are 0.8-1.0 for SAC/SPA, 0.10-0.11 for REP/SPA and 1.1-1.3 for SiO2/SPA. In this case, the water absorption ratio can drop to 4.25%.
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