4.7 Article

Utilizing of neodymium vanadate nanoparticles as an efficient catalyst to boost the photocatalytic water purification

Journal

JOURNAL OF ENVIRONMENTAL MANAGEMENT
Volume 230, Issue -, Pages 266-281

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jenvman.2018.09.080

Keywords

NdVO4; Nanostructures; Eriochorome Black T; Photocatalytic degradation; Nano-catalyst; Recyclability

Funding

  1. council of Iran National Science Foundation (INSF)
  2. University of Kashan [159271/1892290]

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Neodymium Vanadate (NdVO4) nanostructures were successfully synthesized via a modified solid state method in the presence of ligand. These nanoparticles were further used as a photocatalyst. Primarily the best structural formations and smallest crystallite sizes of the systems were identified and optimized by changing the calcination time, calcination temperature and molar ratio of the ligand. The cationic (Methyl Violet (MV)), and anionic (Eosin Y (EY) and Eriochrome Black T (EBT)) dyes were used as a model to evaluate the photoactivity under UV-Vis irradiation. Several operational factors were examined to improve the photocatalytic efficiency include type of dye, type of light source, pH and dye concentration. As a result, the best efficiency in 5 ppm Eriochorome Black T at pH = 11 was achieved in the presence of 0.05 g NdVO4 nanocatalysts.

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