Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 833, Issue -, Pages 427-432Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2018.12.016
Keywords
WS2 nanospheres; Carbon nanofibers; Dopamine; Electrochemical determination; Uric acid
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Funding
- Technology Foundation for Selected Overseas Chinese Scholar, Ministry of Personnel of China [2015192]
- Postdoctoral Initial Founding of Heilongjiang Province [LBH-Q14117]
- Innovative Talent Fund of Harbin City [2016RAQXJ185]
- Science Funds for the Young Innovative Talents of HUST [201604]
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An electrochemical dopamine (DA) sensor was developed based on WS2 nanospheres-carbon nanofibers (WS2 NSs-CNFs) electrode. Carbon nanofibers (CNFs) were synthesized by electrospinning and then WS2 nanospheres (WS2 NSs) were grown on the CNFs by a hydrothermal process. The WS2 NSs-CNFs composite was used for electrochemical detection of DA in the presence/absence of uric acid. The results show that sugar-gourd shaped WS2 NSs are grown dispersedly on the surface of CNFs. The sensitivity of WS2 NSs-CNFs electrode for DA is 5.36 mu A.mu M-1.cm(-2) in the concentration range of 0.5-60 mu M and the limit of detection (LOD) is 0.01 mu M. Moreover, the electrode also exhibits good selectivity, reproducibility and stability. The WS2 NSs-CNFs electrode was also employed for analysis of the biomolecular content in human urine, exhibiting desirable results.
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